1. WCF is interoperable with other services when compared to .Net Remoting,where the client and service have to be .Net.
2. WCF services provide better reliability and security in compared to ASMX web services.
3. In WCF, there is no need to make much change in code for implementing the security model and changing the binding. Small changes in the configuration will make your requirements.
4. WCF has integrated logging mechanism, changing the configuration file settings will provide this functionality. In other technology developer has to write the code.